【職歴】

2009年4月–2012年3月: 日本学術振興会特別研究員 (DC1)
2012年4月–2013年3月: 日本学術振興会特別研究員 (PD)、名古屋大学大学院理学研究科物質理学専攻（化学系） (伊丹健一郎教授)
2013年4月–2018年8月: 講師　名古屋大学教養教育院
2018年8月–現在: 准教授　名古屋大学大学院理学研究科理学専攻

【兼任】

2013年4月–現在: 協力教員
名古屋大学大学院理学研究科物質理学専攻（化学系）
2013年7月–現在: 共同研究者
　トランスフォーマティブ生命分子研究所(WPI-ITbM), 名古屋大学
2013年10月–2017年10月: 共同研究者
　伊丹分子ナノカーボンプロジェクト(JST-ERATO), 名古屋大学
2017年11月–2020年3月: サブグループリーダー
　伊丹分子ナノカーボンプロジェクト(JST-ERATO), 名古屋大学
2018年8月–2019年3月: 協力教員
　名古屋大学教養教育院

2009: ベストディスカッション賞, （第２１回万有札幌シンポジウム）
2010: 大津会議アワードフェロー（Otsu Conference Award Fellow) (No.001)
2012: 第二回育志賞, （日本学術振興会）
2015: 名古屋大学教養教育院　全学教育担当教員顕彰 （名古屋大学）
2015: 昭和電工研究企画賞, （有機合成化学協会）
2016: 第１１回わかしゃち奨励賞　最優秀賞、（愛知産業科学技術部、 科学技術交流財団、日比科学技術振興財団）
2017: Synlett Best Paper Award 2016
2017: Verder-Scientific Award (IRMAIL Science Grant)
2018: 第３２回若い世代の特別講演会　講演証（日本化学会）
2018: The PCCP prize 2018 （英国王立化学会＆日本化学会）
2019: 第68回日本化学会進歩賞、（日本化学会）
2019: 赤崎賞（名古屋大学）
2020: The 2020 Early Career Advisory Board of ACS Catalysis
2023: Banyu Chemist Award (BCA賞), MSD生命科学財団
2023: 第28回ケイ素化学協会　奨励賞

【原著論文】

[30] Synthesis and properties of helically-folded poly(arylenediethynylene)s
Michihisa Toya, Hideto Ito,* Kenichiro Itami*
Polymer Chemistry, 2021, 12, 3290–3298. [detail] DOI: 10.1039/D1PY00144B

[29] Synthesis of Nitrogen‐Containing Polyaromatics by Aza‐Annulative π‐Extension of Unfunctionalized Aromatics
Kou P. Kawahara, Wataru Matsuoka, Hideto Ito*, Kenichiro Itami*
Angew. Chem. Int. Ed. 2020, 59, 6383-6388. DOI: 10.1002/anie.201913394 【detail】

[28] An axially chiral 1,1′-biazulene and its π-extended derivative: synthesis, structures and properties
Chaolumen, Hideto Ito,* Kenichiro Itami*
Chem. Commun. 2019, 55, 9606-9609 . DOI: 10.1039/C9CC03510A【detail】
Selected as a front cover in volume 55, issume 65.

 

[27] Bay-region Selective Annotative π-Extension (APEX) of Perylene Diimides with Arynes
Takayuki Nakamuro, Kazushi Kumazawa, Hideto Ito,* Kenichiro Itami*
Synlett, 2019, 30, 423–428. DOI: 10.1055/s-0037-1611668.

[26] Discovery of Plant Growth Stimulants by C–H Arylation of 2-Azahypoxanthine
Hiroyuki Kitano, Jae-Hoon Choi, Ayaka Ueda, Hideto Ito , Shinya Hagihara, Toshiyuki Kan , Hirokazu Kawagishi , and Kenichiro Itami
Org. Lett. 2018, 20, 5684–5687. DOI: 10.1021/acs.orglett.8b02407 【detail】
Highlighted in C&EN News

 

[25] Annulative π-Extension of Indoles and Pyrroles with Diiodobiaryls by Pd Catalysis: Rapid Synthesis of Nitrogen-Containing Polycyclic Aromatic Compounds
Hiroyuki Kitano, Wataru Matsuoka, Hideto Ito,* Kenichiro Itami*
Chem. Sci.2018, 9, 7556-7561. DOI: 10.1039/c8sc02802h 【detail】

[24] Palladium-Catalyzed Esterification of Carboxylic Acids with Aryl Iodides
Hiroyuki Kitano, Hideto Ito,* Kenichiro Itami*
Org. Lett.2018, 20, 2428–2432. DOI: 10.1021/acs.orglett.8b00775【detail】
Highlighted as Most read articles (7th May, 2018)

[23] C-H Arylation of Phenanthrene with Trimethylphenylsilane by Pd/o-Chloranil Catalysis: Computational Studies on the Mechanism, Regioselectivity, and Role of o-Chloranil
Mari Shibata, Hideto Ito,* Kenichiro Itami*
J. Am. Chem. Soc. 2018, 140, 2196–2205. DOI: 10.1021/jacs.7b11260【detail】

[22] Oxidative Homocoupling Reaction of Aryltrimethylsilanes by Pd/o-chloranil Catalysis
Mari Shibata, Hideto Ito,* Kenichiro Itami*
Chem. Lett.2017, 46, 1701–1704. DOI: 10.1246/cl.170723.【detail】

[21] Rapid Access to Nanographenes and Fused Heteroaromatics by Palladium-Catalyzed Annulative π-Extension Reaction of Unfunctionalized Aromatics with Diiodobiaryls
Wataru Matsuoka, Hideto Ito,* Kenichiro Itami*
Angew. Chem. Int. Ed. 2017, 56, 12224–12228. DOI:10.1002/anie.201707486 【detail】
Highlighted in Organometallic Chemistry: Current Trends in Organometallic and Synthetic Chemistry

[20] Annulative π-Extension (APEX) of Heteroarenes with Dibenzosiloles and Dibenzogermoles by Palladium/o-Chloranil Catalysis
Kyohei Ozaki, Wataru Matsuoka, Hideto Ito,* Kenichiro Itami*
Org. Lett., 2017, 19, 1930–1933. DOI: 10.1021/acs.orglett.7b00684【detail】

[19] One-Step Annulative p-Extension of Alkynes with Dibenzosiloles Dibenzogermoles by Palladium/o-chloranil Catalysis
Kyohei Ozaki, Keiichiro Murai, Wataru Matsuoka, Katsuaki Kawasumi, Hideto Ito,* and Kenichiro Itami*
Angew. Chem. Int. Ed.2017, 56, 1361–1364. DOI: 10.1002/ange.201610374【detail】
Selected as a Hot Paper
Highlighted in Synfacts

[18] Key Structural Elements of Unsymmetrical Cyanine Dyes for Highly Sensitive Fluorescence Turn-on DNA Probe
Kakishi Uno, Taeko Sasaki, Nagisa Sugimoto, Hideto Ito, Taishi Nishihara, Shinya Hagihara, Tetsuya Higashiyama, Narie Sasaki, Yoshikatsu Sato and Kenichiro Itami*
Chem. Asian J.2017, 12, 233–238. DOI: 10.1002/asia.201601430【detail】
Highlighted in chemistry views
Most accessed article in January 2017 (First Place)
Most accessed article in February 2017 (Third Place)
Most accessed article between March 2016 to February 2017 (22nd Place)
Most accessed article between May 2016 to April 2017 (11th place)

[17]Construction of Covalent Organic Nanotubes by Light-Induced Cross-Linking of Diacetylene-Based Helical Polymers
Kaho Maeda, Liu Hong, Taishi Nishihara, Yusuke Nakanishi, Yuhei Miyauchi, Ryo Kitaura, Naoki Ousaka, Eiji Yashima, Hideto Ito,* and Kenichiro Itami*
J. Am. Chem. Soc. 2016, 138, 11001–11008. DOI: 10.1021/jacs.6b05582 【detail】【press release (JP)】[press release(EN)]

 

 

 

 

Selected as the cover art in J. Am. Chem. Soc. 2016, vol.138, issue 38
Highlighted in JACS SPOTLIGHTS (J. Am. Chem. Soc. 2016, 138, 10717. DOI: 10.1021/jacs.6b08657)
Most Read Article Article (Total 2343 views: accessed in 5th, Sep., 2016)
Highlighted in ChemStation Spotlight Research
Highlighted in Academist Journal
Highlighted in News Paper: 日経産業新聞20160809、中日新聞20160901, 科学新聞20160906

 

 

 

Other highlights
[Web News in Japanese]: マイナビニュース、gunosy、excitedニュース、J-Net21、livedoor、E-start注目記事、日経テクノロジーオンライン、EE Times Japan、Yahoo ニュース、Busicom Post、fabcross for エンジニア、Security Online News、2channel News Navigator、はてなブックマーク、ジョルダンニュース!、ニコニコニュース、gooニュース、NTTドコモ、Mapion、Infoseek、Biglobeニュース、日経プレスリリース、
[Web News in English]:Health Medicine Network, Science Newsline, Physorg.com,  ScienceDaily, nanowerk,  AlphaGalileo, ResearchSEA,  EurekAlert, Space Daily, Scicasts, Nanotechnology Now, Chem Europe, Nano Daily
[Web News in Russian]:RAMBLER NEWS SERVICE,
[Web News in Chinese]:权威国防科技信息门户,
[Web News in Brazil]: Inovação Tecnológica

[16] Macrocyclization by Rh-Catalyzed Cross-Cyclotrimerization of L-Shaped Diynes with Di-tert-butyl Acetylenedicarboxylate: Effect of Bent Linkers of Diynes
S. Nishigaki, Y. Miyauchi, K. Noguchi, H. Ito, K. Itami, Y. Shibata, K. Tanaka*
Eur. J. Org. Chem. 2016, 4668–4673. DOI: 10.1002/ejoc.201600909【detail】

[15] Helically Twisted Tetracene: Synthesis, Crystal Structure, and Photophysical Properties of Hexabenzo[a,c,fg,j,l,op]tetracene
Yuuta Yano, Hideto Ito, Yasutomo Segawa, and Kenichiro Itami
Synlett, 2016, 27, 2081-2084. DOI: 10.1055/s-0035-1561455 【detail】
Selected as Synlett Best Paper Award 2016

[14]. A Theoretical Study on the Strain Energy of Carbon Nanobelts
Yasutomo Segawa, Akiko Yagi, Hideto Ito, and Kenichiro Itami
Org. Lett.2016, 18, 1430–1433. DOI: 10.1021/acs.orglett.6b00365 【detail】

[13]. Pyridylidene ligand facilitates gold-catalyzed oxidative C–H arylation of heterocycles
Kazuhiro Hata, Hideto Ito, Yasutomo Segawa and Kenichiro Itami
Beilstein J. Org. Chem. 2015, 11, 2737. DOI: 10.3762/bjoc.11.295

[12].Concise Synthesis and Facile Nanotube Assembly of a Symmetrically Multi-Functionalized Cycloparaphenylene
Yuta Miyauchi, Shintaro Fujii, Kohei Johmoto, Nobuhiro Yasuda, Hideto Ito, Kenichiro Itami, Hidehiro Uekusa, Manabu Kiguchi, and Ken Tanaka
Chem. Eur. J.2015, 21, 18900. DOI: 10.1002/chem.201504185.
selected as Hot Paper

[11]. One-shot K-region-selective Annulative π-Extension for Nanographene Synthesis and Functionalization
Kyohei Ozaki, Katsuaki Kawasumi, Mari Shibata, Hideto Ito, and Kenichiro Itami
Nature Commun. 2015, 6, 6251. DOI: 10.1038/ncomms7251.【detail】
Highlighted in News Papers (Chunichi Shinbun, Nikkan Kogyo Shimbun, Zaikeishinbun)
   Highlighted in Science Portal, Scicasts, Phys Org, AZO NANO, nano werk, Science Daily, Asia Research News, Eurek Alert.

[10]. Thiophene-Based, Radial π-Conjugation: Synthesis, Structure, and Photophysical Properties of Cyclo-1,4-phenylene-2’,5’-thienylenes
Hideto Ito, Yukari Mitamura, Yasutomo Segawa and Kenichiro Itami
Angew. Chem. Int. Ed. 2015, 54, 159-163. DOI: 10.1002/anie.201409389【detail】
   Selected as a inside cover picture in issue 1, 2015.
   Highlighted in Synfacts 2015, 11,141.

[9]. One-shot Indole-to-Carbazole π-Extension by Pd-Cu-Ag Trimetallic System
Kyohei Ozaki, Hua Zhang, Hideto Ito, Aiwen Lei and Kenichiro Itami
Chem. Sci.2013, 4, 3416–3420, DOI: 10.1039/C3SC51447A 【detail】

Most Read Articles in June and July in 2013
Selected as “HOT Chem Sci articles for June” in 2013
   Selected as Back Cover in issue 9, 2013
   Highlighted in Synfacts
   Selected as “Top 25 most-read Chemical Science articles in 2013”

[8]. Construction of Eight-Membered Carbocycles through Gold Catalysis with Acetylene-Tethered Silyl Enol Ethers
Tomohiro Iwai, Hiori Okochi, Hideto Ito and Masaya Sawamura
Angew, Chem. Int. Ed., 2013, 52, 4239–4242. DOI: 10.1002/anie.201300265 

[7]. Use of a Semihollow-Shaped Triethynylphosphane Ligand for Efficient Formation of Six- and Seven-Membered Ring Ethers through Gold(I)-Catalyzed Cyclization of Hydroxy-Tethered Propargylic Esters
Hideto Ito, Ayumi Harada, Hirohisa Ohmiya, Masaya Sawamura
Adv. Synth. Catal., 2013, 355, 647–652.DOI: 10.1002/adsc.201200949

[6]. Formation of Quaternary Carbon Centers via Highly Regioselective Hydroformylation with Catalytic Amounts of a Reversibly Bound Directing Group
Yusuke Ueki, Hideto Ito, Ippei Usui, Bernhard Breit
Chem. Eur. J., 2011, 17, 8555–8558. DOI: 10.1002/chem.201101186

[5]. Intramolecular Hydroamination of Alkynic Sulfonamides Catalyzed by Gold–Triethynylphosphine Complex: Construction of Azepine Frameworks by 7-Exo–dig Cyclization
Hideto Ito, Tomoya Harada, Hirohisa Ohmiya, Masaya Sawamura
Beilstein J. Org. Chem., invited paper, 2011, 7, 951-959. DOI: 10.3762/bjoc.7.106

[4].  Construction of Methylenecycloheptane Frameworks through 7-Exo–Dig Cyclization of   Acetylenic Silyl Enol Ethers Catalyzed by Triethynylphosphine–Gold Complex
Hideto Ito, Hirohisa Ohmiya, Masaya Sawamura
Org. Lett. 2010, 12, 4380–4383.DOI: 10.1021/ol101860j

[3].  General and Functional Group-Tolerable Approach to Allenylsilanes by Rhodium-Catalyzed Coupling between Propargylic Carbonates and a Silylboronate
Hirohisa Ohmiya, Hideto Ito, and Masaya Sawamura
Org. Lett. 2009, 11, 5618–5620. DOI: 10.1021/ol902339a

[2].  Cyclization of Non-Terminal Alkynic b-Keto Esters Catalyzed by Gold(I) Complex with a Semihollow, End-Capped Triethynylphosphine Ligand
Hideto Ito, Yusuke Makida, Atsuko Ochida, Hirohisa Ohmiya, Masaya Sawamura
Org. Lett.2008, 10, 5051–5054. DOI:10.1021/ol802079r

[1].  Using Triethynylphosphine Ligands Bearing Bulky End Caps to Create a Holey Catalytic Environment: Application to Gold(I)-Catalyzed Alkyne Cyclizations
Atsuko Ochida, Hideto Ito, Masaya Sawamura
J. Am. Chem.Soc, 2006, 128, 16486-16487.DOI:10.1021/ja066800c

【Reviews】

 

[8] Heteroatom-Embedding Annulative π-Extension (Hetero-APEX) Reactions – An Overview
Hideto Ito,* Kou. P. Kawahara, Kenichiro Itami*
Synthesis, in press. DOI: 10.1055/a-2169-4078 [detail]

[7] Construction of Heptagon‐Containing Molecular Nanocarbons
Chaolumen, Iain A. Stepek, Keigo E. Yamada, Hideto Ito,* Kenichiro Itami*
Angew. Chem. Int. Ed., 2021, 60, 23508–23532. https://doi.org/10.1002/anie.202100260

[6] A Quest for Structurally Uniform Graphene Nanoribbons: Synthesis, Properties, and Applications
Yuuta Yano, Nobuhiko Mitoma, Hideto Ito,* Kenichiro Itami*
J. Org. Chem. 2020, 86, 4-33. DOI: 10.1021/acs.joc.9b02814 【detail】
Perspective review in the special issue on “Functional Organic Materials”
Selected as a cover picture in vol.85 issue 1.

 

[5] Polycyclic Arene Synthesis by Annulative π-Extension
Hideto Ito, Yasutomo Segawa, Kei Murakami, Kenichiro Itami*
J. Am. Chem. Soc. 2019, 141, 3-10. DOI: 10.1021/jacs.8b09232 【detail】

 

[4] Recent advances in acetylene-based helical oligomers and polymers: Synthesis, structures, and properties
Michihisa Toya, Hideto Ito* and Kenichiro Itami*
Tetrahedron Lett (digest paper), 2018, 59, 1531–1547. DOI: 10.1016/j.tetlet.2018.03.018 【detail】

[3] Annulative π-Extension (APEX): An Enabling Reaction for Rapid Access to Fused Aromatics, Heteroaromatics, and Nanographenes
Hideto Ito,* Kyohei Ozaki, and Kenichiro Itami*
Angew. Chem. Int. Ed. 2017, 56, 11144–11164. DOI: 10.1002/anie.201701058.【detail】

 

[2]. Structurally Uniform and Atomically Precise Carbon Nanostructures
Yasutomo Segawa, Hideto Ito, and Kenichiro Itami
Nature Rev. Mater.2016, 1, 15002.（創刊号）DOI: 10.1038/natrevmats.2015.2[detail]
highlighted in natureasia.com

[1]. Oxidative Cross-Coupling Reaction by Gold/Selectfluor^® Catalysis
Hideto Ito
Journal of Synthetic Organic Chemistry, Japan, 2013, 76, 1075–1076. DOI: 10.5059/yukigoseikyokaishi.71.1075

[2]. 理系基礎化学実験、第１版、第９冊、第10冊
村田静昭、浦野扶美、吉村正宏、伊藤英人　共著、2015年2月、2016年2月、学術図書出版、ISBN: 978-4-7806-0143-5

[1]. Cross-Dehydrogenative-Coupling Reactions without Metals
Hideto Ito, Kirika Ueda, and Kenichiro Itami
From C-H to C-C Bonds : Cross-Dehydrogenative-Coupling (Eds: Chao-Jun Li, DOI: 10.1039/9781782620082), Chapter 8,
Royal Society of Chemistry, 2015, 153–196. DOI: 10.1039/9781782620082-00153.

【Research Grants】Grant Name (Grant Number), Foundation, Direct Cost
Principle Investigator:
FY2009-2011  Grant-in-Aid for JSPS Fellows (JP09J01922), Japan Society for the Promotion of Science, 2,100,000 JPY
FY2012  Grant-in-Aid for JSPS Fellows (JP12J30002), Japan Society for the Promotion of Science, 1,300,000JPY
FY2014-2016  Grant-in-Aid for Encouragement of Young Scientists (B) (JP26810057), Japan Society for the Promotion of Science, 3,100,000JPY
FY2014-2015  Grant for Japan-Related Research Project, Sumitomo Foundation, 1,300,000JPY
FY2016-2017 Grant-in-Aid for Scientific Research on Innovative Areas (JP16H00907), Science of Atomic Layer Systems, Japan Society for the Promotion of Science, 3,200,000 JPY
FY2016 Showa Denko Award in Synthetic Organic Chemistry, Japan, 500,000 JPY
FY2017 Wakashachi Incentive Award Grand Prize, 300,000JPY
FY2018 Daiko Foundation, 4,000,000 JPY
FY2017-2019 Grant-in-Aid for Challenging Research (Exploratory) (JP17K19155), Japan Society for the Promotion of Science, 5,000,000JPY
FY2018–2020 Grant- in-Aid for Scientific Research (B) (18H02019), Japan Society for the Promotion of Science, 13,700,000JPY
FY2020-2021 Grant-in-Aid for Challenging Research (Exploratory) (JP20K21192), Japan Society for the Promotion of Science, 5,00,000JPY
FY2021 Grant- in-Aid for Scientific Research (B) (21HXXXX), Japan Society for the Promotion of Science, 4,500,000JPY

Co-Investigator
FY2020-2021 Grant-in-Aid for Specially Promoted Research (PI: Hirokazu Kawagishi) (JP20H05620), Science of fairy chemicals and their application developement
FY2019-2021 CREST (PI: Hajime Ito), Japan Science and Technology Agency (JST)

【担当授業】

2020-現在: 理学研究科　准教授
春学期：月曜２限　有機化学３（化学科３年生）、火曜3限　化学講究I（分担、化学科２年生）
水曜３限　基礎セミナーA（全学１年生） 化学でひもとくニセ科学
有機化学実験（分担、化学科3年生）、Current Organic Chemistry（分担、G30）
秋学期：有機化学特論II（化学科3年生）
通年：有機化学講究I-IV
2019: 理学研究科　准教授
春学期：月曜２限　有機化学３（化学科３年生）、Current Organic Chemistry（分担）
秋学期：金曜２限　物質と化学（分担、理系学部１年生）
2013-2018: 教養教育院化学実験実験担当講師
理系基礎科目化学実験　春学期：水曜３、４限（G30）、木曜４、５限（工学部）、金曜４、５限（工学部）
秋学期：火曜３、４限（理学部）、金曜４、５限（農学部）

【招待講演・発表リスト(click here)】

Hideto Ito